GOLD-LEAF, or BEATEN GOLD, is gold beaten with a hammer into exceeding thin leaves, so that it is computed, that an ounce may be beaten into 1600 leaves, each three inches square, in which state it takes up more than 159,052 times its former surface.
The preparation of gold leaf, according to Dr Lewis, is as follows:
"The gold is melted in a black-lead crucible, with some
some borax, in a wind furnace, called by the workmen a wind hole: as soon as it appears in perfect fusion, it is poured out into an iron ingot mould, six or eight inches long, and three quarters of an inch wide, previously greased, and heated, so as to make the tallow run and smoke, but not to take flame. The bar of gold is made red hot, to burn off the unctuous matter, and forged on an anvil into a long plate, which is further extended, by being passed repeatedly between polished steel rollers, till it becomes a ribbon as thin as paper. Formerly the whole of this extension was procured by means of the hammer, and some of the French workmen are still said to follow the same practice: but the use of the flattening mill both abridges the operation, and renders the plate of more uniform thickness. The ribbon is divided by compasses, and cut with sheers into equal pieces, which consequently are of equal weights: these are forged on an anvil till they are an inch square; and afterwards well nealed, to correct the rigidity which the metal has contracted in the hammering and flattening. Two ounces of gold, or 960 grains, the quantity which the workmen usually melt at a time, make 150 of these squares, whence each of them weighs six grains and two fifths; and as 902 grains of gold make a cubic inch, the thickness of the square plates is about the 766th part of an inch.
"In order to the further extension of these pieces into fine leaves, it is necessary to interpose some smooth body between them and the hammer, for softening its blow, and defending them from the rudeness of its immediate action: as also to place between every two of the pieces some proper intermedium, which, while it prevents their uniting together, or injuring one another, may suffer them freely to extend. Both these ends are answered by certain animal membranes.
"The goldbeaters use three kinds of membranes; for the outside cover, common parchment made of sheep skin; for interlaying with the gold, first the smoothest and closest vellum, made of calf skin; and afterwards the much finer skins of ox gut, stript off from the large straight gut slit open, curiously prepared on purpose for this use, and hence called gold-beater's skin. The preparation of these last is a distinct business, practised by only two or three persons in the kingdom, some of the particulars of which I have not satisfactorily learned. The general process is said to consist, in applying one upon another, by the smooth sides, in a moist state, in which they readily cohere and unite inseparably; stretching them on a frame, and carefully scraping off the fat and rough matter, so as to leave only the fine exterior membrane of the gut; beating them between double leaves of paper, to force out what unctuous may remain in them; moistening them once or twice with an infusion of warm spices; and lastly, drying and pressing them. It is said, that some calcined gypsum, or plaster of Paris, is rubbed with a hare's foot both on the vellum and the ox gut skins, which fills up such minute holes as may happen in them, and prevents the gold leaf from sticking, as it would do to the simple animal membrane. It is observable, that, notwithstanding the vast extent to which the gold is beaten between these skins, and the great tenuity of the skins themselves, yet they sustain continual repetitions of the process for several months,
without extending or growing thinner. Our workmen find, that, after 70 or 80 repetitions, the skins, though they contract no flaw, will no longer permit the gold to extend between them; but that they may be again rendered fit for use by impregnating them with the virtue which they have lost, and that even holes in them may be repaired by the dexterous application of fresh pieces of skin: a microscopic examination of some skins that had been long used plainly showed these repairs. The method of restoring their virtue is said in the Encyclopédie to be, by interlaying them with leaves of paper moistened with white wine vinegar, beating them for a whole day, and afterwards rubbing them over as at first with plaster of Paris. The gold is said to extend between them more easily, after they have been used a little, than when they are new.
"The beating of the gold is performed on a smooth block of black marble, weighing from 200 to 600 pounds, the heavier the better; about nine inches square on the upper surface, and sometimes less, fitted into the middle of a wooden frame, about two feet square, so as that the surface of the marble and the frame form one continuous plane. Three of the sides are furnished with a high ledge; and the front, which is open, has a leather flap fastened to it, which the gold-beater takes before him as an apron, for preserving the fragments of gold that fall off. Three hammers are employed, all of them with two round and somewhat convex faces, though commonly the workman uses only one of the faces: the first, called the cutch hammer, is about four inches in diameter, and weighs 15 or 16 pounds, and sometimes 20, though few workmen can manage those of this last size: the second, called the shoddering hammer, weighs about 12 pounds, and is about the same diameter: the third, called the gold hammer, or finishing hammer, weighs 10 or 11 pounds, and is nearly of the same width. The French use four hammers, differing both in size and shape from those of our workmen: they have only one face, being in figure truncated cones. The first has very little convexity, is near five inches in diameter, and weighs 14 or 15 pounds: the second is more convex than the first, about an inch narrower, and scarcely half its weight: the third, still more convex, is only about two inches wide, and four or five pounds in weight: the fourth or finishing hammer is near as heavy as the first, but narrower by an inch, and the most convex of all. As these hammers differ so remarkably from ours, I thought proper to insert them, leaving the workmen to judge what advantage one set may have above the other.
"A hundred and fifty of the pieces of gold are interlaid with leaves of vellum, three or four inches square, one vellum leaf being placed between every two of the pieces, and about 20 more of the vellum leaves on the outsides; over these is drawn a parchment case, open at both ends, and over this another in a contrary direction, so that the assemblage of gold and vellum leaves is kept tight and close on all sides. The whole is beaten with the heaviest hammer, and every now and then turned upside down, till the gold is stretched to the extent of the vellum; the case being from time to time opened for discovering how the extension goes on, and the packet, at times, bent and rolled
Gold. rolled as it were between the hands, for procuring sufficient freedom to the gold, or, as the workmen say, to make the gold work. The pieces, taken out from between the vellum leaves, are cut in four with a steel knife; and the 600 divisions, hence resulting, are interlaid, in the same manner, with pieces of the ox-gut skins five inches square. The beating being repeated with a lighter hammer till the golden plates have again acquired the extent of the skins, they are a second time divided in four: the instrument used for this division is a piece of cane cut to an edge, the leaves being now so light, that the moisture of the air or breath condensing on a metalline knife would occasion them to stick to it. These last divisions being so numerous, that the skins necessary for interposing between them would make the packet too thick to be beaten at once, they are parted into three parcels, which are beaten separately, with the smallest hammer, till they are stretched for the third time to the size of the skins: they are now found to be reduced to the greatest thinness they will admit of; and indeed many of them, before this period, break or fail. The French workmen, according to the minute detail of this process given in the Encyclopédie, repeat the division and the beating once more; but as the squares of gold, taken for the first operation, have four times the area of those used among us, the number of leaves from an equal area is the same in both methods, viz. 16 from a square inch. In the beating, however simple the process appears to be, a good deal of address is requisite, for applying the hammers so as to extend the metal uniformly from the middle to the sides: one improper blow is apt not only to break the gold leaves, but to cut the skins.
“ After the last beating, the leaves are taken up by the end of a cane instrument, and, being blown flat on a leather cushion, are cut to a size, one by one, with a square frame of cane made of a proper sharpness, or with a frame of wood edged with cane: they are then fitted into books of 25 leaves each, the paper of which is well smoothed, and rubbed with red bole to prevent their sticking to it. The French, for sizing the leaves, use only the cane knife; cutting them first straight on one side, fitting them into the book by the straight side, and then paring off the superfluous parts of the gold about the edges of the book. The size of the French gold leaves is from somewhat less than three inches to three and three quarters square; that of ours, from three inches to three and three-eighths.
“ The process of gold-beating is considerably influenced by the weather. In wet weather, the skins grow somewhat damp, and in this state make the extension of the gold more tedious: the French are said to dry and press them at every time of using; with care not to overdry them, which would render them unfit for further service. Our workmen complain more of frost, which appears to affect the metalline leaves themselves: in frost, a gold leaf cannot easily be blown flat, but breaks, wrinkles, or runs together.
“ Gold leaf ought to be prepared from the finest gold; as the admixture of other metals, though in too small a proportion to affect sensibly the colour of the leaf, would dispose it to lose of its beauty in the air. And indeed there is little temptation to the workman to use any other; the greater hardness of alloyed gold
occasioning as much to be lost in point of time and labour, and in the greater number of leaves that break, as can be gained by any quantity of alloy that would not be at once discoverable by the eye. All metals render gold harder and more difficult of extension. Even silver, which in this respect seems to alter its quality less than any other metal, produces with gold a mixture sensibly harder than either of them separately, and this hardness is in no art more felt than in the goldbeater's. The French are said to prepare what is called the green gold leaf, from a composition of one part of copper and two of silver with eighty of gold. But this is probably a mistake: for such an admixture gives no greenness to gold: and I have been informed by our workmen, that this kind of leaf is made from the same fine gold as the highest gold-coloured sort, the greenish hue being only a superficial taint induced upon the gold in some part of the process: this greenish leaf is little otherwise used than for the gilding of certain books.
“ But though the goldbeater cannot advantageously diminish the quantity of gold in the leaf by the admixture of any other substance with the gold, yet means have been contrived, for some particular purposes, of saving the precious metal, by producing a kind of leaf called party gold, whose basis is silver, and which has only a superficial coat of gold upon one side: a thick leaf of silver and a thinner one of gold, laid flat on one another, heated and pressed together, unite and cohere; and being then beaten into fine leaves, as in the foregoing process, the gold, though its quantity is only about one fourth of that of the silver, continues everywhere to cover it, the extension of the former keeping pace with that of the latter.
But it is observed by Mr Nicholson, that pure gold is too ductile to be worked between the goldbeater's skin. The newest skins will work the finest gold, and make the thinnest leaf, because they are the smoothest. Old skins, being rough or foul, require coarser gold. The finer the gold, the more ductile; inasmuch that pure gold, when driven out by the hammer, is too soft to force itself over the irregularities, but would pass round them, and by that means become divided into narrow slips. The finest gold for this purpose has three grains of alloy in the ounce, and the coarsest twelve grains. In general, the alloy is six grains, or one-eightieth part. That which is called pale gold contains three pennyweights of silver in the ounce. The alloy of leaf gold is silver, or copper, or both, and the colour is produced of various tints accordingly. Two ounces and two pennyweights of gold is delivered by the master to the workman, who, if extraordinarily skilful, returns two thousand leaves, or eighty books of gold, together with one ounce and six pennyweights of waste cuttings. Hence one book weighs 4.8 grains; and as the leaves measure 3.3 inches in the side, the thickness of the leaf is one two hundred and eighty-two thousandth part of an inch.
The yellow metal called Dutch gold is fine brass. It is said to be made from copper plates, by cementation with calamine, without subsequent fusion. Its thickness, compared with that of leaf gold, proved as 19 to 4, and under equal surfaces it is considerably more than twice as heavy as the gold. Four. vol. i.
It must be observed, however, that gold is beaten more or less, according to the kind or quality of the work it is intended for; that for the gold-wire-drawers to gild their ingots withal, is left much thicker than that for gilding the frames of pictures, &c. See GILDING.