SPIRITUOUS LIQUORS have in all nations been considered as a proper subject of heavy taxation for the support of the state. This has naturally occasioned a nice examination of their strength. It having been at last found that this was intimately connected with the specific gravity, this has been examined with the most scrupulous attention to every circumstance which could affect it, so that the duties might be exactly proportioned to the quantity of spirit in any strong liquor, independent on every other circumstance of flavour or taste, or other valued quality. The chemist at last found that the basis of all strong liquors is the same, produced by the vinous fermentation of pure saccharine matter dissolved in water. He also found, that whether this vegetable salt be taken as it is spontaneously formed in the juices of plants and fruits, or as it may be formed or extricated from farinaceous fruits and roots by a certain part of the process of vegetation, it produces the same ardent spirit, which has always the same density in every mixture with water. The minute portions of aromatic oils, which are in some degree inseparable from it, and give it a different flavour according to the substance from which it was obtained, are not found to have any sensible effect on its density or specific gravity. This seems very completely established in consequence of the unwearying attempts of the manufacturers to lessen the duties payable on their goods by mixtures of other substances, which would increase their density without making them less palatable. The vigilance of the revenue officers was no less employed to detect every such contrivance. In short, it is now an acknowledged point, that the specific gravity is an accurate test of the strength.
But though this is true in general, we cannot derive much benefit from it, unless we know the precise relation between the strength and the density of a spirituous liquor. Do they increase pari passu, or by what law are they connected? It was natural to expect that equal additions of ardent spirits or alcohol to a given quantity of water would produce equal diminutions of density. Areometers were accordingly made on this principle above 200 years ago, as may be seen in the works of Gafpar Schottus, Sturmius, Agricola, and other old authors. But when mathematical physics became more generally known, this was easily discovered to be erroneous; and it was shown (we think first by Mr Boyle) that equal additions to the specific gravity would be produced by successively taking out of any vessel a certain measure of alcohol and replacing it with an equal measure of water. This was the most convenient discovery for all parties, because then the duties payable on a cask of spirits would be in the exact proportion of the diminution of its density. But it was soon found by those who were appointed guardians of the revenue that this conclusion was erroneous, and that a mixture which appeared by this rule to contain 35 gallons of alcohol, did really contain 35. They found by actually making such a mixture: 18 gallons of alcohol mixed with 18 of water produced only 35 gallons of spirits. The revenue officers, finding that this condensation was most remarkable in mixtures of equal parts of water and the strongest spirits which could then be procured, determined to levy the duties by this mixture; because, whether the spirituous liquor was stronger or weaker than this, it would appear, by its specific gravity, rather stronger than it really was. This sagacious observation, and the simplicity of the composition, which could at all times be made for comparison, seem to be the reasons for our excise offices selecting this mode of estimating the strength and levying the duties. A mixture of nearly equal measures of water and alcohol is called PROOF SPIRIT, and pays a certain duty per gallon; and the strength of a spirituous liquor is estimated by the gallons, not of alcohol, but of proof spirit which the cask contains. But because it might be difficult to procure at all times this proof spirit for comparison, such a mixture was made by order of the board of excise; and it was found, that when six gallons of it was mixed with one gallon of water, a wine gallon of the mixture weighed 7 pounds 13 ounces avoirdupois. The board therefore declared, that the spirituous liquor of which the gallon weighed 7 pounds 13 ounces should be reckoned 1 to 6 or 1 in 7 under proof. This is but an awkward and complex formula; it was in order to suit matters to a mode of examination which had by time obtained the sanction of the board. Mr Clarke, an ingenious artist of that time, had made a hydrometer incomparably more exact than any other, and constructed on mathematical principles, fit for computation. This had a set of weights corresponding to the additions of water or proof spirit, and the mixture 1 to 6 or 1 in 7 was the only one which weighed an exact number of ounces per gallon without a fraction.
Thus stands the excise law; and Clarke's hydrometer is still the instrument of authority, although others have been since constructed by Dicas, Quin, and others, which are much more ingenious and convenient. The mathematician who examines Dicas's hydrometer, with its sliding scale, by which it is adjusted to the different temperatures, and points out the conclusions, will perceive a beautiful and sagacious combination of quantities, which he will find it difficult to bring under any analytical formula. Perhaps Quin's may have some preference in respect of convenience; but facile inventis addere. Mr Dicas's was original.
As naturalists became more accustomed to exact observation in every topic of inquiry, the condensation which obtains in the mixture of different substances became more familiarly known. This evidently affects the present question; and both the excise and the distillers are interested in its accurate decision. This occasioned an application to the Royal Society; and a most scrupulous examination of the strength of spirituous liquors was made by Sir Charles Blagden and Mr Gilpin, of which they have given a very particular account in the Philosophical Transactions for 1790 and 1792.
We have taken notice of this in the article SPECIFIC GRAVITY.