Christopher's St., one of the Caribbee islands, in America, lying to the north-west of Nevis, and about 60 miles west of Antigua. It was formerly inhabited by the French and English; but, in 1713, it was ceded entirely to the latter. In 1782, it was taken by the French, but restored to Britain at the peace. It is about 20 miles in breadth, and seven in length; and has high mountains in the middle, whence rivulets run down. Between the mountains are dreadful rocks, horrid precipices, and thick woods; and in the south west part of the island, hot sulphureous springs at the foot of them. The air is good; the soil light, CHROMATICS;
That part of optics which explains the several properties of the colours of light, and of natural bodies.
Before the time of Sir Isaac Newton, we find no hypothesis concerning colours of any consequence. The opinions of the old philosophers, however, we shall briefly mention, in order to gratify the curiosity of our readers. The Pythagoreans called colour the superficies of body. Plato said that it was a flame issuing from them. According to Zeno, it is the first configuration of matter; and Aristotle said, it was that which moved bodies actually transparent. Des Cartes asserted, that colour is a modification of light; but he imagined, that the difference of colour proceeds from the prevalence of the direct or rotatory motion of the particles of light. Father Grimaldi, Dechales, and many others, thought the difference of colour depended upon the quick or slow vibrations of a certain elastic medium filling the whole universe. Rohault imagined that the different colours were made by the rays of light entering the eye at different angles with respect to the optic axis; and from the phenomena of the rainbow, he pretended to calculate the precise quantity of the angle that constituted each particular colour. Lastly, Dr Hooke, the rival of Newton, imagined that colour is caused by the sensation of the oblique or uneven pulse of light; and this being capable of no more than two varieties, he concluded there could be no more than two primary colours.
In the year 1666, Sir Isaac Newton began to investigate this subject; and finding the coloured image of an object invested by the sun, formed by a glass prism, to be of an oblong, Sir Isaac and Newton. and not of a circular form, as, according to the laws of refraction, it ought to be, he began to conjecture that light is not homogeneous; but that it consists of rays, some of which are much more refrangible than others. See this discovery fully explained and ascertained under the article Optics.
This method of accounting for the different colours of bodies, from their reflecting this or that kind of rays most copiously, is so easy and natural, that Sir Isaac's system quickly overcame all objections, and to this day continues to be almost universally believed. It is now acknowledged, that the light of the sun, which to us seems perfectly homogeneous and white, is composed of no fewer than seven different colours, viz. red, orange, yellow, green, blue, purple, and violet or indigo. A body which appears of a red colour hath the property of reflecting the red rays more powerfully than any of the others; and so of the orange, yellow, green, &c. A body which is of a black colour, instead of reflecting, absorbs all or the greatest part of the rays that fall upon it; and, on the contrary, a body which appears white reflects the greatest part of the rays indiscriminately, without separating the one from the other.
The foundation of a rational theory of colours being thus laid, it next became natural to inquire, by what peculiar mechanism in the structure of each particular body it was fitted to reflect one kind of rays more than another? This Sir Isaac Newton attributes to the density of these bodies. Dr Hooke had remarked, that thin transparent substances, particularly water and soap blown into bubbles, exhibited various colours according to their thicknesses; though, when they have a considerable degree of thickness, they appear colourless; and Sir Isaac himself had observed that as he was compressing two prisms hard together, in order to make their sides (which happened to be a little convex) to touch one another, in the place of contact they were both perfectly transparent, as if they had been but one continued piece of glass. Round the point of contact, where the glasses were a little separated from each other, rings of different colours appeared. To observe more nicely the order of the colours produced in this manner, he took two object-glasses; one of them a plano-convex one belonging to a 14 feet refracting telescope, and the other a large double convex one for a telescope of about 50 feet; and laying the former of them upon the latter, with its plain side downwards, he pressed them slowly together; by which means the colours very soon emerged, and appeared distinct at a considerable distance. Next to the pellucid central spot, made by the contact of the glasses, succeeded blue, white, yellow, and red. The blue was very little in quantity, nor could he discern any violet in it; but the yellow and red were very copious, extending about as far as the white, and four or five times as far as the blue. The next circuit immediately surrounding these, consisted of violet, blue, green, yellow, and red: all these were copious and vivid, except the green, which was very little in quantity, and seemed more faint and dilute than the other colours. Of the other four the violet was the least in extent; and the blue less than the yellow or red. The third circle of colours was purple, blue, green, yellow, and red. In this the purple seemed more reddish than the violet in the former circuit, and the green was more conspicuous; being as brisk and copious as any of the other colours, except the yellow; but the red began to be a little faded, inclining much to purple. The fourth circle consisted of green and red; and of these the green was very copious and lively, inclining on the one side to blue, and on the other to yellow; but in this fourth circle there was neither violet, blue, nor yellow, and the red was very imperfect and dirty. All the succeeding colours grew more and more imperfect and dilute, till after three or four revolutions they ended in perfect whiteness.
As the colours were thus found to vary according to the different distances of the glass plates from each to arise other; our author thought that they proceeded from the different thicknesses of the plate of air intercepted between the glasses; this plate of air being, by the mere circumstance of thickness or thickness, disposed to reflect or transmit this or that particular colour. From this he concluded, as already observed, that the colours of all natural bodies depended on their density, or the bigness of their component particles. He also constructed a table, wherein the thickness of a plate necessary to reflect any particular colour was expressed in parts of an inch divided into 1,000,000 parts.
Sir Isaac Newton, pursuing his discoveries concerning the colours of thin substances, found that the same reflections were also produced by plates of a considerable thickness. There is no glass or speculum, he observes, how well polished soever, but, besides the light which it refracts or reflects regularly, scatters every way irregularly a faint light; by means of which the polished surface, when illuminated in a dark room by a beam of the sun's light, may easily be seen in all positions of the eye. It was with this scattered light that the colours in the following experiments were produced.
The sun shining into his darkened chamber through a hole in the shutter one inch wide, he let the beam of light fall perpendicularly upon a glass speculum concave on one side and convex on the other, ground to a sphere of five feet eleven inches radius, and quicksilvered over on the convex side. Then, holding a quire of white paper at the centre of the sphere to which the speculums were ground, in such a manner as that the beam of light might pass through a little hole made in the middle of the paper, to the speculum, and thence be refracted back to the same hole, he observed on the paper four or five concentric rings of colours, like rainbows surrounding the hole, very much like those which appeared in the thin plates above-mentioned, but larger and fainter. These rings, as they grew larger and larger, became more dilute, so that the fifth was hardly visible; and yet sometimes, when the sun shone very clear, there appeared faint traces of a sixth and seventh.
We have already taken notice, that the thin plates made use of in the former experiments reflected some refraction and reflection of rays in particular parts, and transmitted others in the same parts. Hence the coloured rings appeared variously disposed, according as they were viewed by transmitted or reflected light; that is, according as the plates were held up between the light and the eye, or not. For the better understanding of which we subjoin the following table, wherein on one side are mentioned the colours appearing on the plates by reflected light, and on the other those which were opposite to them, and which became visible when the glasses were held up between the eye and the window. We have already observed, that the centre, when the glasses were in full contact, was perfectly transparent. This spot, therefore, when viewed by reflected light, appeared black, because it transmitted all the rays; and for the same reason it appeared white when viewed by transmitted light.
| Colours by Reflected Light | Colours by Transmitted Light | |---------------------------|-----------------------------| | Black | White | | Blue | Yellowish-red | | White | Black | | Yellow | Violet | | Red | Blue | | Violet | White | | Blue | Yellow | | Green | Red | | Yellow | Violet | | Red | Blue | | Purple | Green | | Blue | Yellow | | Green | Red | | Yellow | Bluish-green | | Red | Red | | Green | Bluish-green | | Red | Red | | Greenish-blue | Red | | Red | |
The colours of the rings produced from reflection by the thick plates, followed the order of those produced by transmission through the thin ones; and by the analogy of their phenomena with those produced from the thin plates, Sir Isaac Newton concluded that they were produced in a similar manner. For he found, that if the quicksilver was rubbed off from the back of the speculum, the glass alone would produce the same rings, but much more faint than before; so that the phenomenon did not depend upon the quicksilver, except in as far as, by increasing the reflection at the back of the glass, it increased the light of the coloured rings. He also found that a speculum of metal only, produced none of these rings; which made him conclude, that they did not arise from one surface only, but depended on the two surfaces of the plate of glass of which the speculum was made, and upon the thickness of the glass between them.
From these experiments and observations, it will be easy to understand the Newtonian theory of colours. Every substance in nature seems to be transparent, provided it is made sufficiently thin. Gold, the most dense substance we know, when reduced into thin leaves, transmits a bluish-green light through it. If, therefore, we suppose any body, gold for instance, to be divided into a vast number of plates, so thin as to be almost perfectly transparent, it is evident that all or greatest part of the rays will pass through the upper plates, and when they lose their force will be reflected from the under ones. They will then have the same number of plates to pass through which they had penetrated before; and thus, according to the number of those plates through which they are obliged to pass, the object appears of this or that colour, just as the rings of colours appeared different in the experiment of the two plates, according to their distance from one another, or the thickness of the plate of air between them.
This theory is adopted by Edward Hufsey Delaval, Mr. Delaval in this Experimental Inquiry into the cause of the various exchanges of colours in opaque and coloured bodies, riments in He endeavours to confirm it by a number of experiments on the infusions of flowers of different colours; but his strongest arguments seem to be those derived from the different tinges given to glass by metallic substances. Here he observes, that each metal gives a tinge according to its specific density: the more dense metals producing the less refrangible colours, and the lighter ones those colours which are more easily refrangible. Gold, which is the densest of all metals, imparts a red colour to glass, whenever it can be divided into particles so minute, that it is capable of being mixed with the materials of which glass is made. It seems indifferent by what means it is reduced to this state, nor can it by any means be made to produce another colour. If it is mixed in large masses without being minutely divided, it imparts no colour to the glass, but remains in its metallic form. Lead, the metal whose density is next in order to that of gold, affords a glass of the colour of the hyacinth; a gem whose distinguishing characteristic is, that it is red with an admixture of yellow, the same colour which is usually called orange. Glasses of lead is mentioned by several authors as a composition proper, without the addition of any other ingredient, for imitating the hyacinth. Silver, next in density to lead, can only be made to communicate a yellow colour to glass. If the metal is calcined with sulphur, it readily communicates this colour. Leaf-silver laid upon red-hot glass, likewise tinges it yellow. When we meet with authors who mention a blue or greenish colour communicated by silver, the cause must have been, that the silver used in such processes was mixed with copper. Mr. Delaval affirms us, from his own experience, that silver purified by the test retains so much copper, that, when melted several times with nitre and borax, it always imparted a green colour at the first and second melting; though afterwards no such colour was obtainable from it. The only colour produced by copper is green. It is indifferent in what manner the copper is prepared in order to tinge the glass, provided it is exposed without any other ingredient to a sufficient degree of heat. If a quantity of salts are added in the preparation, they will, by attenuating the mixture, make the glass incline to blue, the colour next in order; but this happens only when the fire is moderate; for, in a greater degree of heat, the redundant salts, even those of the most fixed nature, are expelled. It is true, that copper is mentioned by some writers as an ingredient in red glass and enamel; but the red, which is the colour of the metal not dissolved or mixed with the glass, remains only while the composition is exposed to such a degree of heat as is too small to melt and incorporate it; for if it be suffered to remain in the furnace a few minutes after the copper is added, the mass will turn out green instead of red. Iron, the metal next in density to copper, is apt to be calcined, or reduced to a ruddy crocus, similar to that ruff which it contracts spontaneously in the air. In this state, it requires a considerable degree of heat to dissolve and incorporate it with glass: till that heat is applied, it retains its ruddy colour; by increasing the heat, it passes through the intermediate colours, till it arrives at its permanent one, which is blue; this being effected in the greatest degree of heat the glass will bear, without losing all colour whatever. Iron vitrified per se is converted into a blue glass. In short, it is indubitable, that iron is the only metal which will, without any addition, impart to the glass a blue colour; for copper will not communicate that colour without the addition of a considerable quantity of salts, or some other matter that attenuates it; and the other metals cannot by any means be made to produce it at all.
These are the principal of Mr Delaval's arguments in favour of Sir Isaac Newton's theory of colours being formed by density. Dr Priestley too has mentioned some which deserve attention. "It was a discovery of Sir Isaac Newton (says he), that the colours of bodies depend upon the thicknesses of the fine plates which compose their surfaces. He hath shown, that a change of the thicknesses of these plates occasions a change in the colour of the body; rays of a different colour being thereby disposed to be transmitted through it; and consequently rays of a different colour reflected at the same place, so as to represent an image of a different colour to the eye. A variation in the density occasions a variation in the colour; but still a medium of any density will exhibit all the colours, according to the thicknesses of it. These observations he confirmed by experiments on plates of air, water, and glass. He likewise mentions the colours which arise on polished steel by heating it, as likewise on bell-metal, and some other metallic substances, when melted and poured on the ground, where they may cool in the open air; and he ascribes them to the scoriae or vitrified parts of the metal, which, he says, most metals, when heated or melted, do continuously protrude and send out to their surfaces, covering them in the form of a thin glassy skin. This great discovery concerning the colours of bodies depending on the thicknesses of the fine plates which compose their surfaces, of whatever density those plates may be, I have been so happy as to hit upon a method of illustrating and confirming by means of electrical experiments. A number of these being received on the surface of any piece of metal, change the colour of it to a considerable distance from the spot on which they were discharged; so that the whole circular space is divided into a number of concentric rings, each of which consists of all the prismatic colours, and perhaps as vivid as they can be produced in any method whatever. Upon showing these coloured rings to Mr Canton, I was agreeably surprised to find, that he had likewise produced all the prismatic colours from all the metals, but by a different operation. He extended fine wires of all the different metals along the surfaces of pieces of glass, ivory, wood, &c.; and when the wire was exploded, he always found them tinged with all the colours. They are not disposed in so regular and beautiful a manner as in the rings I
produced, but they equally demonstrated that none of the metals thus exploded discovers the least preference to one colour more than to another. In what manner these colours are formed it may not be easy to conjecture. In Mr Canton's method of producing them, the metal, or the calcined and vitrified parts of it, seem to be dispersed in all directions from the plate of explosion, in the form of spheres of a very great variety of sizes, tinged with all the variety of colours, and some of them smaller than can be distinctly seen by any magnifier. In my method of making these colours, they seem to be produced in a manner similar to the production of colours on steel and other metals by heat; i.e., the surface is affected without the parts of it being removed from their places, certain plates or laminae being formed of a thickness proper to exhibit the respective colours.
But, however well supported this doctrine of the Newtonian formation of colours by density may be, we find the theory insane author (Dr Priestley), whom we have just now pounced by been arguing for it in his history of electricity, arguing against it in his history of vision. "There are (says he) no optical experiments with which Sir Isaac Newton seems to have taken more pains than those relating to the rings of colours which appear in thin plates; and in all his observations and investigations concerning them, he discovers the greatest sagacity both as a philosopher and mathematician; and yet in no object to which he gave his attention, does he seem to have overlooked more important circumstances in the appearances he observed, or to have been more mistaken with regard to their causes. The former will be evident from the observations of those who succeeded him in these inquiries, particularly those of the Abbé Mazzei. This gentleman, endeavouring to give a curious very high polish to the flat side of an object-glass, happened to be rubbing it against another piece of flat metal by and smooth glass; when he was surprised to find, that the Abbé after this friction, they adhered very firmly together, till at last he could not move the one above the other. But he was much more surprised to observe the same colours between these plane glasses that Newton observed between the convex object-glasses of a telescope and another that is plane. These colours between the plane glasses, the Abbé observes, were in proportion to their adhesion. The resemblance between them and the colours produced by Newton, induced him to give a very particular attention to them; and his observations and experiments are as follows:
"If the surfaces of the pieces of glass are transparent, and well polished, such as are used for mirrors, and the pressure be as equal as possible on every part of the two surfaces, a resistance, he says, will soon be perceived when one of them is made to slide over the other; sometimes towards the middle, and sometimes towards the edges; but wherever the resistance is felt, two or three very fine curve lines will be perceived, some of a pale red, and others of a faint green. Continuing the friction, these red and green lines increase in number at the place of contact, the colours being sometimes mixed without any order, and sometimes disposed in a regular manner. In the last case, the coloured lines are generally concentric circles, or ellipses, or rather ovals, more or less elongated as the surfaces..." surfaces are more or less united. These figures will not fail to appear, if the glasses are well wiped and warmed before the friction.
"When the colours are formed, the glasses adhere with considerable force, and would always continue so without any change in the colours. In the centre of all those ovals, the longer diameter of which generally exceeds ten lines, there appears a small plate of the same figure, exactly like a plate of gold interposed between the glasses; and in the centre of it there is often a dark spot, which absorbs all the rays of light except the violet; for this colour appears very vivid through a prism.
"If the glasses are separated suddenly, either by sliding them horizontally over one another, or by the action of fire, as will be explained hereafter, the colours will appear immediately upon their being put together again, without the least friction.
"Beginning by the slightest touch, and increasing the pressure by insensible degrees, there first appears an oval plate of a faint red, and in the midst of it a spot of light green, which enlarges by the pressure, and becomes a green oval, with a red spot in the centre; and this, enlarging in its turn, discovers a green spot in its centre. Thus the red and the green succeed one another in turns, affuming different shades, and having other colours mixed with them, which will be distinguished presently.
"The greatest difference between these colours exhibited between plane surfaces and those formed by curve ones is, that in the former case pressure alone will not produce them, except in the case above mentioned. With whatever force he compelled them, his attempts to produce the colours were in vain without previous friction. But the reason of this plainly was, that with sliding one of the glasses over the other, they could not be brought to approach near enough for the purpose.
"Having made these observations with plates of glass whose sides were nearly parallel, he got two prisms with very small refracting angles; and rubbing them together, when they were so joined as to form a parallelopiped, the colours appeared with a surprising lustre at the places of contact, owing, he did not doubt, to the separation of the rays of light by the prism. In this case, differently coloured ovals appeared, but the plate of gold in them was much whiter, and only appeared yellow about its edges. The plate having a black spot in its centre, was bordered by a deep purple. He could not perceive any violet by his naked eye, but it might be perceived by the help of a lens with a weak light. It appeared in a very small quantity at the confines of the purple and the blue, and seemed to him to be only a mixture of these two colours. It was very visible in each of the coloured rings by inclining the glasses to the light of the moon. Next to the purple and violet appeared blue, orange, red tinged with purple, light green, and faint purple. The other rings appeared to the naked eye to consist of nothing but faint reds and greens; and they were so shaded that it was not easy to mark their terminations. That the order of these may be compared with Newton's, he gives a view of both in the following table:
| Order of the Colours in the Plane Glasses | Order of the Colours in Newt. Object Glasses | |------------------------------------------|---------------------------------------------| | Black spot | Black | | Whitish oval | Blue | | Yellow border | White | | Deep purple | Yellow | | Blue | Red | | Orange | Violet | | Purple | Blue | | Greenish blue | Green | | Yellow green | Yellow | | Purple red | Red | | Green | Purple | | Red | Blue | | Faint green | Green | | Faint red | Red | | Weak green | Greenish blue | | Light red | Red | | Very faint green | Greenish blue | | Very faint red | Pale red |
"When these coloured glasses were suspended over the flame of a candle, the colours disappeared suddenly, though the glasses still continued to adhere to one another when they were parallel to the horizon. When they were suffered to cool, the colours returned by degrees to their former places, in the order of the preceding table.
"After this the Abbé took two plates much thicker than the former, in order to observe at his leisure the action of fire upon the matter which he supposed to produce the colours; and observed, that as they grew warm, the colours retired to the edges of the glasses, and there became narrower and narrower till they were reduced to imperceptible lines. Withdrawing the flame, they returned to their place. This experiment he continued till the glasses were bent by the violence of the heat. It was pleasant, he says, to observe these colours glide over the surface of the glass as they were purified by the flame.
"At the first our author had no doubt but that these colours were owing to a thin plate of air between the glasses, to which Newton has ascribed them: but the remarkable difference in the circumstances attending those produced by the flat plates, and those produced by the object-glasses of Newton, convinced him that the air was not the cause of this appearance. The colours of the flat plates vanished at the approach of flame, but those of the object-glasses did not. He even heated the latter till that which was next the flame was cracked by the heat, before he could observe the least dilatation of the coloured rings. This difference was not owing to the plane glasses being less compressed than the convex ones; for though the former were compressed even so much by a pair of forceps, it did not in the least hinder the effect of the flame.
"Afterwards he put both the plane glasses and the convex ones into the receiver of an air pump, suspending the former by a thread, and keeping the latter com- pressed by two strings; but he observed no change in the colours of either of them in the most perfect vacuum he could make.
"Notwithstanding these experiments seemed to be conclusive against the hypothesis of these colours being formed by a plate of air, the Abbé frankly acknowledges, that the air may adhere so obstinately to the surface of the glasses as not to be separated from them by the force of the pump; which, indeed, is agreeable to other appearances: but the following experiments of our author make it still more improbable that the air should be the cause of these colours.
"To try the utmost effect of heat upon these coloured plates, after warming them gradually, he laid them upon burning coals; but though they were nearly red, yet when he rubbed them together by means of an iron rod, he observed the same coloured circles and ovals as before. When he ceased to press upon them the colours seemed to vanish; but when he repeated the friction, they returned, and continued till the pieces of glass began to be red-hot, and their surfaces to be united by fusion.
"When the outward surface of one of his plates of glass was quicksilvered, none of these colours were visible, though the glasses continued to adhere with the same force. This he ascribed to the stronger impression made on the eye by the greater quantity of light reflected from the quicksilver.
"Judging from the resemblance between his experiments and those of Sir Isaac Newton, that the colours were owing to the thickness of some matter, whatever that was, interposed between the glasses, the Abbé, in order to verify his hypothesis, tried the experiment on thicker substances. He put between his glasses a little ball of fuel, about a fourth of a line in diameter, and pressed it between the two surfaces, warming them at the same time, in order to disperse the fuel; but though he rubbed them together as before, and used other soft substances besides fuel, his endeavours to produce the colours had no effect. But, rubbing them with more violence in a circular manner, he was surprised on looking at a candle through them, to see it surrounded with two or three concentric rings, very broad, and with very lively delicate colours; namely, a red inclining to a yellow, and a green inclining to that of an emerald. At that time he observed only these two colours; but continuing the friction, the rings assumed the colours of blue, yellow, and violet, especially when he looked through the glasses on bodies directly opposed to the sun. If, after having rubbed the glasses, the thickness was considerably diminished, the colours grew weaker by transmitted light, but they seemed to be much stronger by reflection, and to gain on one side what they lost on the other.
"Our author was confirmed in his opinion, that there must be some error in Newton's hypothesis, by considering, that, according to his measures, the colours of the plates varied with the difference of a millionth part of an inch; whereas he was satisfied that there must have been much greater differences in the distance between his glasses, when the colours remained unchanged.
"If the colour depended upon the thickness only, he thought that the matter interposed between the glasses ought to have given the same colour when it was reduced to a thin plate by simple fusion as well as by friction, and that, in rubbing two plates together, warming them at different times, and compressing them with a considerable force, other colours would have appeared besides those above-mentioned.
"These circumstances made him suspect, that the different thicknesses of the substance interposed between the glasses served only to make them more or less transparent; which was an essential condition in the experiment; and he imagined that the friction diffused over the surface of the thin substance a kind of matter on which the colours are formed by reflected light: for when he held the plates (which gave the colours when the fuel was between them) over the flame of a small candle, the colours fled with great precipitation, and returned to their place without his being able to perceive the least alteration in the fuel.
"He was confirmed in his conjectures, by frequently observing, that when the glasses were separated, at the moment the colours disappeared, they were covered with the same greasy matter, and that it seemed to be in the very same state as when they were separated without warming. Besides, having often repeated the same experiment with different kinds of matter, he found that the degree of heat that dispersed the colours was not always sufficient to melt it; which difference was more sensible in proportion as the matter interposed was made thinner.
"Instead of the fuel, he sometimes made use of Spanish wax, resin, common wax, and the sediment of urine. He began with Spanish wax, on account of its remarkable transparency in Mr Hauksbee's electrical experiments; but he had much difficulty in making it sufficiently thin by friction, being often obliged to warm his glasses, to seize the moment of fusion, which continued but a short time, and to hazard the burning of his fingers.
"The experiment at length succeeding, the Spanish wax appeared with its opacity and natural colour when it reflected the light, but they both disappeared in the transmitted light. He observed the same rings in it as in the fuel; and indeed he could perceive but little difference between the colour of fuel, Spanish wax, common wax, or resin; except that this last substance did not make the colours so vivid, on account of the too great transparency of its particles.
"The sediment of urine had something more particular in its appearance, as its colours were more lively. Holding it above the flame, its colour disappeared; and keeping it in that situation, there were formed, upon its surface, ramifications, like those of the hoar-frost, which disappeared as the glasses grew cold. There were the same ramifications both upon the fuel and the wax, but they were not so considerable. The glasses which had Spanish wax and resin between them adhered with so much force, that they could not be separated without the help of fire; and when they began to grow warm, they separated with a noise like that of a glass breaking in the fire, though the glasses were not broken, and the matter between them was not melted.
"Separating the glasses which he first used very suddenly," suddenly, he observed upon their surface very thin vapours, which formed different colours, but presently vanished altogether.
"To try the effect of vapour, he breathed upon one of his plates of glass, and observed that the vapours which adhered to the glasses sometimes formed, before they were entirely dispersed, a surprising variety of colours. This experiment, he observes, does not always succeed at the first trial. The glasses must be breathed upon several times, and care must be taken to wipe it every time with one's hand, both to take off the moisture, and also to make upon the glasses a kind of furrows, which contribute very much to the variety of colours, by making inequalities in the thicknesses of the vapours. It is necessary, also, that the glasses on which these experiments are made have no quicksilver upon them.
"When the particles of water which formed this vapour were too thick to exhibit these colours, he struck them several times with his pencil, in order to attenuate them; and then he saw an infinity of small coloured threads which succeeded one another with great rapidity.
"Putting a drop of water between two pieces of common glass, he observed that the compression of them produced no colour; but if, while they were compressed, the water was made to pass from one place to another, it left behind it large spots, red, yellow, green, purple, &c., and the spots assumed different colours with a surprising rapidity, and presented to the eye a most beautiful variety of shades.
"In order to determine with greater certainty whether they were vapours that caused the colours in his first observations, he first breathed upon one of his plates of glass, and then rubbed them against one another, when the colours appeared in the same order as before, but darker, and dispersed in confusion in the places occupied by the vapours; but when he made use of fire to dissipate the watery particles, the colours resumed their lustre.
"Newton, having introduced a drop of water between his two object-glasses, observed, that in proportion as the water insinuated itself between the glasses, the colours grew fainter, and the rings were contracted; and attributing these colours to the thicknesses of the plate of water, as he ascribed the former to that of the plate of air, he measured the diameters of the coloured rings made by the plate of water, and concluded that the intervals between the glasses at the similar rings of these two mediums were nearly as three to four; and thence he inferred, that in all cases, these intervals would be as the sines of the refractions of these mediums.
"The Abbé Mazeas, in order to assure himself whether, agreeable to this rule, the coloured rings of his glasses depended upon the thicknesses of the water only, dipped one of the edges of his coloured glasses in a vessel of water, having taken care to wipe and warm them well, before he produced his colours by friction. The water was a considerable time in rising as high as the glasses; and in proportion as it ascended, he perceived a very thin plate of water, which seemed to pass over the matter which he thought produced the colours, without mixing with it; for beyond this plate of water, he still perceived the colours in the same place and order, but deeper and darker; and holding the glasses above the flame of a candle, he saw the colours go and come several times as he moved them nearer to or farther from the flame. He then moistened both the glasses more than before; and rubbing them as usual, he always saw the same appearance; and seizing the moment when the colours had disappeared to separate the glasses, he always found that they were wet. On this account, he thought that it could not be the water on which the colour depended, but some substance much more sensible to heat. He also thought that these coloured rings could not be owing to the compression of the glasses; or that, if this circumstance did contribute anything to them, it served rather to modify than to generate them.
"M. du Tour gave particular attention to the preceding observations of the Abbé Mazeas. He repeated these observations, particularly comparing them with those of Sir Isaac Newton. He is so far from supposing a plate of air to be necessary to the formation of these coloured rings, that he thinks the reason of their not appearing between the flat plates of glasses is the adhesion of the air to their surfaces; and that mere pressure is not sufficient to expel it; except, as the Abbé Mazeas observed, the rings had before been made in the same place; in which case, simple apposition without friction is sufficient; the air, probably, not having had time to apply itself so closely to the surface of the glasses. The contact of some other substances, M. du Tour observes, is not so prejudicial in this experiment as that of air; for he found, that, if he only gave the plates a slight coating of any kind of grease, the rings would appear without friction. Also dipping them slightly in water, or wiping them with his finger, would answer the same purpose. He verified his conjectures by means of the air-pump: for, dipping two pieces of glasses in water, one of which had been wiped, and the other not, the former appeared to have no bubbles adhering to it, when the air was exhausted, whereas the other had.
"When one of the glasses is convex, our author observes, that the particles of air may more easily make their escape by pressure only; whereas their retreat is in a manner cut off when they are compressed between two flat surfaces. The air-pump, he found, was not able to detach these particles of air from the surfaces to which they adhere; leaving these flat plates for a considerable time in an exhausted receiver, was not sufficient to prepare them so well for the experiment as wiping them.
"Besides the observations on the colours of thin plates, it has been seen that Sir Isaac Newton imagined he could account for the colours exhibited by thick ones in some cases in a similar manner; particularly in those curious experiments in which he admitted a beam of light through a hole in a piece of pasteboard, and observed the rings of colours reflected back upon it by a concave glass mirror of equal thickness in all places. These experiments were resumed, and happily pursued by the Duke de Chaulnes, who ascribed these colours to the inflection of light*. Chance* See Op- led the duke to observe, that when the nearer surface of the glass mirror was clouded by breathing upon it, fo so as lightly to tarnish it, a white diffused and vivid light was seen upon the pasteboard, and all the colours of the rings became much stronger, and more distinct. This appearance he made constant by moistening the surface of the mirror with a little milk and water, and suffering it to dry upon it.
"In all his experiments upon this subject, he found, that when the rays fell converging on the surface of the mirror, the rings were hardly visible; when they fell parallel upon it, as they must have done in all the experiments of Newton, they appeared sufficiently distinct; but when, by means of a convex lens placed in the hole of the window, they were made to diverge from the centre of the sphere to which the mirror was ground, so that they fell perpendicularly on the surface of the mirror, the colours were as vivid as he could make them. In this case he could remove the reflected image to a great distance from the hole, without making the rings disappear; and he could plainly perceive them to arise from their central spots, which changed their colours several times.
"The effect of tarnishing the mirror convinced him, that these coloured rings depended on the first surface of the mirror; and that the second surface, or that which reflected them after they had passed the first, only served to collect them and throw them upon the pasteboard in a quantity sufficient to make them visible; and he was confirmed in his supposition by the following experiments.
"He took a plano-convex object-glass, of six feet focus, and placed it six feet from the pasteboard with its convex side towards it. By this means the rays which fell upon that surface, after being refracted there, were transmitted through the thickness of the glass, parallel to one another, and fell perpendicularly on the plane surface that reflected them, and, in their return, would be collected upon the pasteboard. In these circumstances the rings appeared very distinct after he had tarnished the convex surface, which in this position was next to the light.
"Turning the same glass the contrary way, so that the plane surface was towards the pasteboard, he could perceive none of the rings at the distance of six feet; but they were visible at the distance of three feet; because at that distance the second surface reflected the rays by its concavity directly towards the pasteboard.
"These two experiments demonstrate the use of the second surface of the mirror, and show the manner of placing it to most advantage. Those that follow show the use of the first surface with respect to these rings; and he was led to make them by the casual observation above mentioned.
"Newton, he observes, had remarked, that when he made use of a mirror of the same focus with the first he had used, but of twice the thickness, he found the diameter of the rings much smaller than before. This observation the duke thought favourable to his own conclusions; for if these rings depend upon the first surface, the nearer it is to the second, which only reflects the ray transmitted from it, the larger they ought to appear upon the pasteboard.
"To ascertain this fact, he thought of making use of two moveable surfaces; and to make use of a micrometer to measure the distance between them with exactness. For this purpose he took a metallic mirror belonging to a reflecting telescope, being part of a sphere of ten feet radius; and he fixed it firm upon a foot in which was a groove that carried a light frame, to which was fastened a thin piece of talk tarnished with milk and water. The frame that supported the piece of talk could either be brought into contact with the mirror, or be removed to the distance of eight or nine inches from it, and the micrometer showed to the utmost exactness the least motion of the frame.
"Having placed this mirror ten feet from the pasteboard, that is, at the distance of the radius of its own sphere, he observed the rings to appear very distinct; the form of his mirror being very true: but the diameter of the rings upon the pasteboard varied with the distance of the talk from the mirror: so that they were very large when the talk was near the mirror, and very small when it was placed at the distance of seven or eight inches.
"These experiments proved, that the rings were formed by the first surface, and reflected by the second; but it still remained to be determined in what manner they were formed. He imagined that the small pencils of rays that were transmitted through the pores of the glass, or any other transparent substance, might suffer a kind of inflection, which might change the cylinder which they formed into a truncated cone, either by means of their different degrees of inflexibility, or by the different distances at which they pass by the edges of the small hole through which they are transmitted. Pursuing this idea, he thought of making use of some body, the pores of which were of a known and determined shape. Instead, therefore, of the piece of talk, he placed a piece of fine linen in the above-mentioned frame, stretching it as even as possible, to make the pores formed by the threads more exact, and more permeable by the light; and he soon found, with great pleasure, that his conjecture was verified: for instead of the circular rings which he had before, they were now manifestly square, though their angles were a little rounded; and they were coloured as the others, though the light was not very vivid, on account of the quantity that was stopped by the muslin.
"When, instead of the muslin, he stretched across his frame fine silver wires exactly parallel, at the distance of about three quarters of an inch, or a whole line from one another, without any other wires across them; instead of the rings which he had seen before, there was nothing upon the pasteboard but a gleam of white light divided by many small streaks, coloured in a very vivid manner, and in the same manner as the rings."
Thus we have another hypothesis of the formation of colours, namely, by the inflection of light in its theory of passage out from between the solid and impenetrable colours, particles of which bodies are composed. It is, however, very difficult, upon the hypotheses either of Sir Isaac Newton, or that of the duke de Chaulnes, to give a reason why bodies that are not entirely white, should not appear variously coloured. For it appears From Sir Isaac Newton's experiments, that plates of different density are capable of exhibiting the same colours; and that where a plate is continually varying in density, it will produce all the colours. Now it is evident, evident, that the plates of which we suppose all natural bodies to be composed, must be similar to one that is perpetually varying in its thickness; for supposing the plates of which any substance is composed to be of any determinate thickness, 9 millionth parts of an inch for instance; such of the rays as are reflected from this plate will be red. But if any of them penetrate to the depth of 11½ of these parts, they will be reflected of a violet colour, &c., and thus must alloy and obscure the red; and so of others. If we suppose the colours to be produced by inflection, it will be equally difficult to account for some particular rays being inflected and others not; seeing we observe that all of them are capable of being inflected by every substance whatever, when they pass very near it. In some cases, too, colours are produced when the light is neither refracted nor inflected, as far as we can judge; and this seems to obscure the theory of chromatics more than anything we have yet mentioned.
As the experiments we are now about to mention are of the greatest importance, and in direct terms contradict one of Sir Isaac Newton's, we shall give a full account of them, from Priestley's History of Vision, &c., with his remarks thereon.
The experiment in question is the eighth of Newton's second book of Optics: "He (Sir Isaac Newton's experiments) found, he says, that when light goes out of air through several contiguous refracting mediums, as through water and glass, and thence goes out again into air, whether the refracting surfaces be parallel or inclined to one another, that light, as often as, by contrary refractions, it is so corrected, that it emerges in lines parallel to those in which it was incident, continues ever after to be white; but if the emergent rays be inclined to the incident, the whiteness of the emerging light will, by degrees, in passing on from the place of emergence, become tinged at its edges with colours. This he tried by refracting light with prisms of glass, placed within a prismatic vessel of water.
"By theorems, deduced from this experiment, he infers, that the refraction of the rays of every sort, made out of any medium into air, are known by having the refraction of the rays of any one sort; and also, that the refraction out of one medium into another is found as often as we have the refractions out of them both into any third medium.
"On the contrary, a Swedish philosopher (M. Klingenstierna) observes*, that in this experiment, the rays of light, after passing through the water and the glass, though they come out parallel to the incident rays, will be coloured; but that the smaller the glass prism is, the nearer will the result of it approach to Newton's description.
"This paper of M. Klingenstierna, being communicated to Mr Dollond by M. Mallet, made him entertain doubts concerning Newton's report of the result of his experiment, and determined him to have recourse to experiments of his own.
"He therefore cemented together two plates of parallel glass, at their edges, so as to form a prismatic vessel when stopped at the ends or bases; and the edge being turned downwards, he placed in it a glass prism with one of its edges upwards, and filled up the vacancy with clear water; so that the refraction of the prism was contrived to be contrary to that of the water, in order that a ray of light, transmitted through both these refracting mediums, might be affected by the difference only between the two refractions. As he found the water to refract more or less than the glass prism, he diminished or increased the angle between the glass plates, till he found the two contrary refractions to be equal, which he discovered by viewing an object through this double prism. For when it appeared neither raised nor depressed, he was satisfied that the refractions were equal, and that the emergent rays were parallel to the incident.
"Now, according to the prevailing opinion, he observes, that the object should have appeared through this double prism in its natural colour; for if the difference of refrangibility had been in all respects equal, in the two equal refractions, they would have rectified each other. But this experiment fully proved the fallacy of the received opinion, by showing the divergency produced by the light by the glass prism to be almost double that of that by the water; for the image of the object, though not at all refracted, was yet as much infected with prismatic colours as though it had been seen through a glass wedge only whose angle was near 30 degrees.
"This experiment is the very same with that of Sir Isaac Newton above mentioned, notwithstanding the result was so remarkably different: but Mr Dollond affirms us, that he used all possible precaution and care in his process; and he kept his apparatus by him, that he might evince the truth of what he wrote, whenever he should be properly required to do it.
"He plainly saw, however, that if the refracting angle of the water-vessel could have admitted of a sufficient increase, the divergency of the coloured rays would have been greatly diminished, or entirely rectified; and that there would have been a very great refraction without colour, as he had already produced a great discolouring without refraction; but the inconvenience of so large an angle as that of the prismatic vessel must have been, to bring the light to an equal divergency with that of the glass prism, whose angle was about 60°, made it necessary to try some experiments of the same kind with smaller angles.
"Accordingly he got a wedge of plate-glass, the angle of which was only nine degrees; and, using it in the same circumstances, he increased the angle of the water-wedge, in which it was placed, till the divergency of the light by the water was equal to that by the glass; that is, till the image of the object, though considerably refracted by the excess of the refraction of the water, appeared nevertheless quite free from any colours proceeding from the different refrangibility of the light.
"Notwithstanding it evidently appeared, I may say Defences of to almost all philosophers, that Mr Dollond had made Sir Isaac a real discovery of something not comprehended in the optical principles of Sir Isaac Newton, it did not appear to sensible a man, and to good a mathematician, as Mr Murdoch is universally acknowledged to be. Upon this occasion he interposed in the defence, as he imagined, of Sir Isaac Newton; maintaining, that Mr Dollond's positions, which he says, he knows not by what mischance have been deemed paradoxes in Sir Isaac's theory of light, are really the necessary consequences of it. He also endeavours to show, that Sir Isaac might not be mistaken in his account of the experiment above mentioned. But admitting all that he advances in this part of his defence, Newton must have made use of a prism with a much smaller refracting angle than, from his own account of his experiments, we have any reason to believe he ever did make use of.
"The fact probably was, that Sir Isaac deceived himself in this case, by attending to what he imagined to be the clear consequences of his other experiments; and though the light he saw was certainly tinged with colours, and he must have seen it to be so, yet he might imagine that this circumstance arose from some imperfection in his prisms, or in the disposition of them, which he did not think it worth his while to examine. It is also observable, that Sir Isaac is not so particular in his description of his prisms, and other parts of his apparatus, in his account of this experiment, as he generally is in other cases, and therefore probably wrote his account of it from his memory only.
Much has been said on this experiment; and it is thought very extraordinary, that a man of Sir Isaac's accurate attention should have overlooked a circumstance, the effect of which now appears to be so confiderable. But it has happily occurred to Mr Mitchel, that, as Sir Isaac Newton observes, he used to put saccharum saturni into his water to increase its refractive power, the lead, even in this form, might increase the diffusive refraction, as it does in the composition of glaas; and if so, that this would account for Newton's not finding his diffusive power of water less than that of the glaas prisms, which he otherwise ought to have done, if he had tried the experiment as he said he did.
Accordingly he included a prism of glaas in water, as highly impregnated with saccharum saturni as it would bear, the proportion of saccharum to water being about as 5 to 11. When the image, seen through the water (so impregnated) and a glaas prism, was in its natural place, it still was coloured, though very little; he thought not more than a fourth part as much as when seen through plain water, and the prism in its natural place; so that he had no doubt, but that, if his prism had had a little less of the diffusing power, its errors would have been perfectly corrected."
Besides the experiments of Mr Delaval above related; and which were made on the colours of transparent bodies, he has lately published an account of some made upon the permanent colours of opaque substances; the discovery of which must be of the utmost consequence in the arts of colour-making and dyeing. These arts, he observes, were in very remote ages carried to the utmost height of perfection in the countries of Phoenicia, Egypt, Palestine, India, &c., and that the inhabitants of these countries also excelled in the art of imitating gems, and tingling glaas and enamel of various colours. The colours used in very ancient paintings were as various as those now in use, and greatly superior both in beauty and durability. The paints used by Apelles were so bright, that he was obliged to glaze his pictures with a dark coloured varnish, lest the eye should be offended by their excessive brightness; and even these were inferior to what had been used among the ancient Egyptians. Pliny complains that the art of painting was greatly decayed in his time; and the moderns were not furnished with any means of retrieving the art, until they began to avail themselves of experimental observations.
The changes of colour in permanently coloured bodies, our author observes, are produced by the same laws which take place in transparent colours, depending chiefly on the experiments by which they can be divided into investigated consist chiefly of various methods of uniting the colouring particles into larger, or dividing them into smaller masses. Sir Isaac Newton made his experiments chiefly on transparent substances; and in the few places where he treats of others, acknowledges his deficiency of experiments. He makes the following remark, however, on those bodies which reflect one kind of light and transmit another, viz. that "If these glasses or liquors were so thick and massy that no light could get through them, he questioned whether they would not, like other opaque bodies, appear of one and the same colour in all positions of the eye; though he could not yet affirm it from experience."
It was the opinion of this great philosopher, that all coloured matter reflects the rays of light, some reflecting the more refrangible, and others the less refrangible rays more copiously; and that this is not only a true reason of these colours, but likewise the only reason. He was likewise of opinion, that opaque bodies reflect the light from their interior surface by some power of the body evenly diffused over and external to it. With regard to transparent-coloured liquors, he expresses himself in the following manner: "A transparent body, which looks of any colour by transmitted light, may also look of the same colour by reflected light; the light of that colour being reflected by the farther surface of that body, or by the air beyond it: and then the reflected colour will be diminished, and perhaps cease, by making the body very thick, and pitching it on the back side to diminish the reflection of its farther surface, so that the light reflected from the tingling particles may predominate. In such cases, the colour of the reflected light will be apt to vary from that of the light transmitted."
To investigate the truth of these opinions, Mr Delaval entered upon a course of experiments with transparent coloured liquors and glasses, as well as with opaque and semi-transparent bodies. From these he discovered several remarkable properties of the colouring matter; particularly, that in transparent coloured substances it does not reflect any light; and when, by intercepting the light which was transmitted, it is hindered from passing through such substances, they do not vary from their former colour to any other, but become entirely black (a).
This incapacity of the colouring particles of trans-
(a) Here our author observes, that he makes use of the word colour only to express those called primary; such parent bodies to reflect light, being deduced from very numerous experiments, may therefore be held as a general law. It will appear the more extensive, if we consider, that, for the most part, the tinging particles of liquors or other transparent substances are extracted from opaque bodies; that the opaque bodies owe their colours to those particles, in like manner as the transparent substances do; and that by the loss of them they are deprived of their colours.
For making his experiments, Mr Delaval used small phials of flint-glass, whose form was a parallelopiped, and their height, exclusive of the neck, about two inches, the base about an inch square, and the neck two inches in length. The bottom and three sides of each of these phials were covered with a black varnish; the cylindrical neck, and the anterior side, except at its edges, being left uncovered. He was careful to avoid any crevices in the varnish, that no light might be admitted except through the neck or anterior side of the phials.
In these experiments it is of importance to have the phials perfectly clean; and as many of the liquors are apt to deposit a sediment, they ought to be put into the phials only at the time the experiments are to be made. The uncovered side of the phials should not be placed opposite to the window through which the light is admitted; because in that situation the light would be reflected from the farther side of the phial; and our author observes, that smooth black substances reflect light very powerfully. But as it is a principal object in the experiment, that no light be transmitted through the liquor, this is best accomplished by placing the uncovered side of the phial in such a situation that it may form a right angle with the window.
With these precautions, our author viewed a great number of solutions, both of coloured metallic salts and of the tinging matter of vegetables; universally observing, that the colour by reflection was black, whatever it might be when viewed by transmitted light. If these liquors, however, are spread thin upon any white ground, they appear of the same colour as when viewed by transmitted light; but on a black ground they afford no colour, unless the black body be polished; in which case the reflection of the light through it produces the same effect as transmission.
The experiments with tinged glasses were in many respects analogous to those with transparent-coloured liquors. For these he made several parcels of colourless glasses, principally using one composed of equal parts of borax and white sand. The glass was reduced to powder, and afterwards ground, together with the ingredients by which the colours were imparted. "This method (says he) of incorporating the tinging particles is greatly preferable to mixing them with the raw materials; and the glasses thus composed excel most others in hardness, being scarcely inferior in lustre to real gems."
The result of all the experiments made in this manner was, that when matter is of such thinness, and the tinge so diluted that light can be transmitted through it, the glasses then appear vividly coloured; but when they are in larger masses, and the tinging matter is more densely diffused through them, they appear black; for these, as well as the transparent-coloured liquids, show their colour only by transmission. The following experiments were made with a view to determine the proportion of tinging matter which produces colour or blackness.
1. Glass was tinged green by adding to it \( \frac{1}{6} \) of its weight of copper; and that whether the latter was used in its metallic or calcined state.
2. A blue glass was made by the addition of zaffre, a portion of a purple one by manganese, a red glass by gold, and tinging yellow glasses by silver and calcined iron. A yellow matter glass resembling a topaz was likewise made by the addition of a small quantity of charcoal in powder. The same colour was likewise procured by the addition of wheat-flour, rosin, and several other inflammable matters. Small pieces of each of these glasses being ground by a lapidary, resembled gems of their different colours.
3. Having formed pieces of such glasses about two inches thick, he inclosed them in black cloth on all sides, except their farther and anterior surfaces. In this situation each of them showed a vivid colour when light was transmitted through them; but when the posterior surface was likewise covered with the cloth to prevent this transmission, no other colour than black was exhibited by any of them.
4. When plates of transparent-coloured glass, somewhat thicker than common window-glass, were made use of, they always exhibited their colours by transmitted light.
5. On intercepting the light transmitted through these coloured plates, they as constantly appeared black when placed in such a direction as to form a right angle with the window.
From these phenomena Mr Delaval deduced the following observations: 1. That the colouring particles do not reflect any light. 2. That a medium, such as Sir Isaac Newton has described, is diffused over both the anterior and farther surfaces of the plates, whereby objects are equally and regularly reflected as by a mirror. Hence, when it is said that light is reflected by the surface of any substance, it should be understood from this expression, that the reflection is effected by the medium diffused over its surface.
6. When a lighted candle is placed near one of those on the recoloured plates, the flame is reflected by the medium of which is diffused over the anterior surface. The image of a candle thus reflected entirely resembles the flame in size and coloured colour; being scarcely diminished, and not in the least glasses tinged by the coloured glass.
7. If the plate be not so intensely coloured, or so maffy, as to hinder the transmission of the light of the candle, there appears a secondary image of the flame, which is reflected by the medium contiguous to the farther surface of the glass; and as the light thus reflected passes through the coloured glass, it is tinged very vividly.
8. When such a mixture of them as does not compose whiteness, or any of the gradations between white and black; such as are called by Sir Isaac Newton, gray, dun, or russet brown. 8. When the glass used in this experiment is of a green colour, the image of the flame is always of a bright green; and when glasses of other colours are used, that of the secondary flame is always the same with that of the glass.
9. The secondary image is less than that reflected from the anterior surface. This diminution is occasioned by the loss of that part of the light which is absorbed in passing through the coloured glass. For whenever any medium transmits one sort of rays more copiously than the rest, it stops a great part of the differently coloured rays. Much more light also is lost in passing through coloured than transparent substances. In making these observations, it is proper to choose coloured plates of glass which are not in every part of an equal thickness, that the secondary image may not coincide with that reflected from the anterior surface, and be intercepted by it.
10. When the plates are so thick, and so copiously coloured, that the light cannot penetrate to their farther surface, they appear intensely black in whatever direction they are viewed, and afford no secondary image, but only reflect, from their anterior surface, the flame, or any other objects that are opposed to them. These objects are represented in their own proper colours, and are as free from tinge as those reflected from quicksilvered glasses, or specula made of white metals.
Hence again it is manifest, that the colouring particles do not possess any share of reflective power; for if they had any share in this reflection, they would certainly impart some share of colour to the light they reflected. Hence also it appears, that transparent coloured bodies, in a solid state, possess no more reflective power than those in a fluid state.
Our author next considers the colouring particles themselves, pure, and unmixed with other media. In order to procure masses made up of such particles, several transparent coloured liquors were reduced to a solid consistence by evaporation. By employing a gentle heat, the colouring matter may thus remain unimpaired; and is capable of having its particles again separated by water or other liquids, and tinged them as before.
In this state the colouring particles reflect no light, and therefore appear uniformly black, whatever substance they have been extracted from. In the course of his experiments, Mr Delaval made use of the infusions of brazil wood, logwood, fustic, turmeric, red saunders, alkanet, sap-green, kermes, and all the other transparent coloured liquors he had tried before, among which were infusions of red and yellow flowers, without observing the least variation in the result.
Some liquors are apt to become totally opaque by evaporation; the reason of which may be the crystallization of saline matters, or the coalescence of the particles into masses, differing considerably in density from the menstrua in which they were dissolved. When this opacity takes place, our author has constantly observed, that they became incapable of entering the pores of wool, silk, or other matters of that kind, or of adhering to their surface; and consequently unfit for the purposes of dyeing. This he supposes to arise from their increased bulk; for the attractive force by which the particles cohere together is weakened in proportion as their bulk increases; so that the degree of magnitude of the colouring particles, which is essential to the opacity of liquors, is inconsistent with the minutest requisite for dyeing. An instance of this is given in an infusion of fustic. Having infused some of this wood in such a quantity of water, that the latter was saturated with the colouring particles, he evaporated the liquor to a solid consistence with an uninterrupted, but very gentle heat. During every part of the process the liquor continued transparent, and the solid extract yielded by it transmitted a yellow colour when spread thin, but appeared black when thicker masses were viewed. Having prepared another pint of this liquor, he evaporated half the water, and allowed the remainder to become cold. In this state it became turbid and opaque; on filtering, a transparent tincture passed through, an opaque fecula remaining on the paper. This fecula did not adhere to the paper, but was easily separable from it; on being dried, it appeared white with a slight tinge of yellow; but was nevertheless soluble in water, and by solution gave a liquid in all respects similar to the original infusion. "From these circumstances (says he) it appears that a given proportion of water, or a sufficient degree of heat, is requisite to the solution of the colouring particles of fustic. And experience evinces, that those particles which are too gross to pass through filtering paper, are incapable of entering the pores, or firmly cohering to the surface of bodies. Many ingredients, such as the colouring particles of logwood, kermes, and various other matters, are soluble in water in every proportion; and therefore their infusions are not subject to become opaque or turbid during their evaporation. The solid extracts obtained by evaporation reflect no colour, but are black.
Our author also formed solid masses by mixing a small quantity of drying oil with pigments which consist chiefly of colouring matter; as Prussian blue, indigo, and sap-green. These paints likewise exhibit their respective colours only by transmitted light, appearing entirely black when viewed by reflection. Instances of blackness arising from this density of the colouring matter, may be observed in several kinds of fruits, as black currants, cherries, &c., for the juices of these appear red when spread thin on a white ground, or otherwise viewed by transmitted light.
Mr Delaval's next attempt was to consider the action and properties of the colouring particles of opaque bodies themselves, and the means by which these colours are produced. Here our author endeavours to prove, that these colours of opaque bodies appear on the same principles as those already mentioned, which seem black when very dense, but show their proper tinge when spread thin upon a white ground. On this subject the following experiments were made:
1. Grasps, and other green leaves of plants, were digested in rectified spirit of wine; by which means a transparent green tincture was obtained. One of the vials formerly mentioned being filled with this liquid, it was observed to transmit a vivid green colour; but the other part of the tincture, which was contiguous to the uncovered side of the vial, reflected no light, and therefore appeared black.
2. Having poured some of the tincture into a China cup, the bottom was thereby made to look green, exactly.