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FLUIDITY

Volume 8 · 1,012 words · 1815 Edition

is by Sir Isaac Newton defined to be, that property of bodies by which they yield to any force impressed, and which have their parts very easily moved among one another.

To this definition some have added, that the parts of a fluid are in a continual motion. This opinion is supported by the solution of salts, and the formation of tinctures. If a small bit of saffron is thrown into a phial full of water, a yellow tincture will soon be communicated to the water to a considerable height; though the phial is allowed to remain at rest; which indicates a motion in those parts of the fluid which touch the saffron, by which its colouring matter is carried up.

With regard to water, this can scarce be denied; the constant exhalations from its surface show, that there must be a perpetual motion in its parts from the ascent of the steam through it. In mercury, where insensible evaporation does not take place, it might be doubted; and accordingly the Newtonian philosophers in general have been of opinion, that there are some substances essentially fluid, from the spherical figure of their constituent particles. The congelation of mercury, however, by an extreme degree of cold, demonstrates that fluidity is not essentially inherent in mercury more than in other bodies.

That fluids have vacuities in their substance is evident, because they may be made to dissolve certain bodies without sensibly increasing their bulk. For example, water will dissolve a certain quantity of salt; after which it will receive a little sugar, and after that a little alum, without increasing its first dimensions. Here we can scarce suppose any thing else than that the saline particles were interposed between those of the fluid; and as, by the mixture of salt and water, a considerable degree of cold is produced, we may thence easily see why the fluid receives these substances without any increase of bulk. All substances are expanded by heat, and reduced into less dimensions by cold; therefore, if any substance is added to a fluid, which tends to make it cold, the expansion by the bulk of the substance added will not be so much perceived as if this effect had not happened; and if the quantity added be small, the fluid will contract as much, perhaps more, from the cold produced by the mixture, than it will be expanded from the bulk of the salt. This also may let us know with what these interfaces between the particles of the fluid were filled up; namely, the element of fire or heat. The saline particles, up- on their solution in the fluid, have occupied these spaces; and now the liquor being deprived of a quantity of this element equal in bulk to the salt added, feels sensibly colder.

As, therefore, there is scarce any body to be found, but what may become solid by a sufficient degree of cold, and none but what a certain degree of heat will render fluid; the opinion naturally arises, that fire is the cause of fluidity in all bodies, and that this element is the only essentially fluid substance in nature. Hence we may conclude, that those substances which we call fluids are not essentially so, but only assume that appearance in consequence of an intimate union with the element of fire; just as gums assume a fluid appearance on being dissolved in spirit of wine, or salts in water.

Upon these principles Dr Black mentions fluidity as an effect of heat. The different degrees of heat which are required to bring different bodies into a state of fluidity, he supposes to depend on some particulars in the mixture and composition of the bodies themselves: which becomes extremely probable, from considering that we change the natural state of bodies in this respect, by certain mixtures; thus, if two metals are compoundcd, the mixture is usually more fusible than either of them separately. See Chemistry Index.

It is certain, however, that water becomes warmer by being converted into ice; which may seem contradictory to this opinion. To this, however, the doctor replies, that fluidity does not consist in the degree of sensible heat contained in bodies, which will affect the hand or a thermometer; but in a certain quantity which remains in a latent state. This opinion he supports from the great length of time required to melt ice; and to ascertain the degree of heat requisite to keep water in a fluid state, he put five ounces of water into a Florence flask, and converted it into ice by means of a freezing mixture put round the flask. Into another flask of the same kind he put an equal quantity of water cooled down nearly to the freezing point, by mixing it with snow, and then pouring it off. In this he placed a very delicate thermometer; and found that it acquired heat from the air of the room in which it was placed: seven degrees of heat were gained the first half hour. The ice being exposed to the same degree of heat, namely, the air of a large room without fire, it cannot be doubted that it received heat from the air as fast as the water which was not frozen; but, to prevent all possibility of deception, he put his hand under the flask containing the ice, and found a stream of cold air very sensibly defending from it, even at a considerable distance from the flask; which undeniably proved, that the ice was all that time absorbing heat from the air. Nevertheless, it was not till 11 hours that the ice was half melted, though in that time it had absorbed so much heat as ought to have raised the thermometer to 140°; and even after it was melted, the temperature of the water was found scarce above the freezing point: so that as the heat which entered could not be found in the melted ice, he concluded that it remained concealed in the water, as an essential ingredient of its composition.