A clear liquid fluid, capable of hardening without losing its transparency, used by painters, gilders, &c., to give a lustre to their works, in order to preserve them and defend them from the air.
A coat of varnish ought to possess the following properties:
1st. It must exclude the action of the air; because wood and metals are varnished to defend them from decay and rust. 2nd. It must resist water; for otherwise the effect of the varnish could not be permanent. 3rd. It ought not to allow such colours as are intended to be preserved by themselves. It is necessary therefore that a varnish should be easily extended or spread over the surface, without leaving pores or cavities; that it should not crack or scale; and that it should resist water. Now resins are the only bodies that possess these properties. Resins consequently may be used as the bases of varnish. The question which of these presents itself must then be, how to dispose them for his use; and for this purpose they must be dissolved, as minutely divided as possible, and combined in such a manner that the imperfections of those which might be dissolved to scale may be corrected by others.
Resins may be dissolved by three agents:
1st. By fixed oil. 2nd. By volatile oil. 3rd. By alcohol.
And accordingly we have three kinds of varnish: the fat or oily varnish, essential varnish, and spirit varnish.
Before a resin is dissolved in a fixed oil, it is necessary to render the oil drying. For this purpose the oil is boiled with metallic oxides; in whose operation the mucilage of the oil combines with the metal, while the oil itself unites with the oxygen of the oxide. To accelerate the drying of this varnish, it is necessary to add oil of turpentine. The essential varnishes consist of a solution of resin in oil of turpentine. The varnish being applied, the essential oil flies off, and leaves the resin. This is used only for paintings.
When resins are dissolved in alcohol, the varnish dries very speedily, and subject to crack; but this fault is corrected by adding a small quantity of turpentine to the mixture, which renders it brighter, and less brittle when dry.
We shall now give the method of preparing a number of varnishes for different purposes.
Varnish for Toilet-boxes, Cases, Fans, &c.—Dissolve two ounces of gum mastich and eight ounces gum sandarach in a quart of alcohol; then add four ounces of Venice turpentine.
Varnish for Wainscots, Cane Chairs, Iron Chairs, &c.—Dissolve in a quart of alcohol eight ounces of gum sandarach, two ounces of seed lac, four ounces of rosewood; then add six ounces of Venice turpentine. If the varnish is wished to produce a red colour, more of the lac and less of sandarach should be used, and a little dragon's blood should be added. This varnish is so thick that two layers of it are equal to four or five of another.
Varnish for Fiddles, and other Musical Instruments.—Put four ounces of gum sandarach, two ounces of gum mastich, two ounces of gum lac, an ounce of gum eleocharis, into a quart of alcohol, and hang them over a slow fire till they are dissolved; then add two ounces of turpentine.
Varnish in order to employ Vermilion for painting Equi-
Gold-coloured Varnish.—Pound separately four ounces of stick lac, four ounces of gamboge, four ounces of dragon's blood, four ounces of annatto, and one ounce of saffron; put each of them separately into a quart of alcohol, and expose them for five days in a narrow-mouthed bottle to the sun, or keep them during that time in a very warm room, shaking them every now and then to hasten the solution. When they are melted, mix them together. More or less of each of these ingredients will give the different tints of gold according as they are combined. In order to make silver imitate gold exactly when covered with this varnish, the quantity of ingredients must be somewhat greater. The method of gilding silver leaf, &c., with this varnish, is as follows: The silver leaf being fixed, in the same manner as gold leaf, by the interposition of proper glutinous matters, the varnish is spread upon the piece with a brush or pencil. The first coat being dry, the piece is again and again washed over with the varnish till the colour appears sufficiently deep. What is called gilt leather, and many picture frames, have no other than this counterfeit gilding. Washing them with a little rectified spirit of wine affords a proof of this; the spirit dissolving the varnish, and leaving the silver leaf of its own whiteness. For plain frames, thick tinfoil may be used instead of silver. The tin leaf, fixed on the piece with glue, is to be burnished, then polished with emery and a fine linen cloth, and afterwards with putty applied in the same manner: being then lacquered over with the varnish five or six times, it looks very nearly like burnished gold. The same varnish, made with a less proportion of the colouring materials, is also applied on works of brass; both for heightening the colour of the metal to a resemblance with that of gold, and for preserving it from being tarnished or corroded by the air.
Oil Varnishes.—Gum copal and amber are the substances principally employed in oil varnishes. They possess the properties necessary for varnishes, solidity and transparency. The copal being whitest, is used for varnishing light, the amber for dark colours. It is best to dissolve them before mixing them with the oil, because by this means they are in less danger of being scorched, and at the same time the varnish is more beautiful. They should be melted in a pot on the fire; they are in a proper state for receiving the oil when they give no resistance to the iron spatula, and when they run off from it drop by drop. The oil employed should be a drying oil, and perfectly free from grease. It should be poured into the copal or amber by little and little, constantly stirring the ingredients at the same time with the spatula. When the oil is well mixed with the copal or amber, take it off the fire; and when it is pretty cool, pour in a greater quantity of the essence of turpentine than the oil that was used. After the varnish is made, it should be passed through a linen cloth. Oil varnishes become thick by keeping; but when they are to be used, it is only necessary to pour in a little essence of turpentine, and to put them for a little on the fire. The turpentine is necessary in oil varnishes to make them dry properly; generally twice as much of it is used as of oil. Less is necessary in summer than in winter. Too much oil hinders the varnish from drying; but when too little is used, it cracks and does not spread properly. We shall subjoin the most useful oil varnishes.
White Copal Varnish.—On sixteen ounces of melted copal pour four, six, or eight ounces of linseed oil, boiled and quite free from grease. When they are well mixed, take them off the fire (not forgetting to stir them properly); and when pretty cool, pour in sixteen ounces of the essence of Venice turpentine. Pass the varnish through a cloth. Amber varnish is made in the same way.
Black Varnish for Coaches and Iron Work.—This varnish is composed of bitumen of Palestine, rosin, and amber, melted separately, and afterwards mixed; the oil is then added, and afterwards the turpentine, as directed above. The usual proportions are, twelve ounces of amber, two ounces of rosin, two ounces of bitumen, six of oil, and twelve of the essence of turpentine. Golden coloured varnish may be made also by substituting linseed oil for alcohol.
**Essential Oil Varnishes.**—The only essential oil varnishes used are for pictures. Picture varnishes should be white, light, and quite transparent, which will preserve the colours without giving them any disagreeable tint; and it should be possible to take them off the picture without injuring it. They are usually made of gum mastic and turpentine dissolved together in some essential oil. The varnish is passed through a cloth, and allowed to clarify. It is applied cold to the picture.
**Varnish for Glass in order to preserve it from the rays of the Sun.**—Pulverize a quantity of gum adragant, and let it dissolve for twenty-four hours in the white of eggs well beat up; then rub it gently on the glass with a brush.
Varnishes, before they are used, should be carefully kept from dust, which would spoil them; and they should be kept in a vessel quite clean and dry. When used, they should be lifted lightly with a brush, and spread upon a ground altogether free from dirt and moisture. The substance, after being varnished, should be exposed to the heat of the sun, or placed in a warm room covered with a glass case, to keep out all filth. Oil varnishes require more heat than alcohol varnishes. The varnish should be put on very quickly, making great strokes with the pencil or brush, taking care that these strokes never cross one another; it should be spread equally, and never thicker than a leaf of paper; a second coat should never be put on till the first is quite dry. If the varnish, after being put on, becomes dull and uneven, it must be taken off entirely, and new varnish applied.
When wainscot is to be varnished, it is first painted of a wooden colour. This colour is made by infusing in water either red or yellow ochre (according to the colour wished for), terra ombria (a kind of ochre) and white lead; into this as much as necessary is put of parchment paste. Two thin coats of this are to be put on, and, after they are quite dry, the varnish.
Varnishes are polished with pumice-stone and Tripoli earth. The pumice-stone must be reduced to an impalpable powder, and put upon a piece of serge moistened with water; with this the varnished substance is to be rubbed lightly and equally. The Tripoli must also be reduced to a very fine powder, and put upon a clean woollen cloth moistened with olive oil, with which the polishing is to be performed. The varnish is then to be wiped with soft linen, and, when quite dry, cleaned with starch or Spanish white, and rubbed with the palm of the hand or with a linen cloth.
To recover colours or varnish, and to take off the dirt and filth which may adhere to them, a ley is used made of potash and the ashes of lees of wine. Take forty-eight ounces of potash, and sixteen of the above mentioned ashes, put them into six quarts of water, and the ley is made. Instead of the ashes an equal quantity of potash would probably do as well. To clean dirty colours, dilute some of this ley with four times its quantity of water, and rub the picture with it; then wash it with river water; and when dry, give it a coat or two of varnish. In order to take off a varnish, wash it with the above mentioned ley, then with water, and then lift it off the substance on which it was with any iron instrument.